Justin Timberlake & Chris Stapleton Shine In Showstopping CMAs Performance

Justin
Timberlake, who grew up in Memphis, Tennessee, tapped into his country roots
with a show-stopping performance at the Country Music Association Awards.

Timberlake
sang alongside popular songwriter and singer Chris Stapleton at the Bridgestone
Arena in Nashville, Tennessee, on Wednesday night. They strummed their guitars
while singing “Tennessee Whiskey,” which Stapleton wrote, and
followed that with Timberlake’s tune, “Drink You Away.”

The
audience was in awe: Timberlake’s wife, actress Jessica Biel, watched excitedly
and bopped her head, while Keith Urban recorded the performance with his phone.

PHOTOS: CMA Awards 2015: Red Carpet Arrivals!

Stapleton
went on to win new artist and album of the year for “Traveller.”

“This
is unbelievable. I don’t know what to say. I don’t know what to think,”
said Stapleton who has written for Kenny Chesney, George Strait and others.
“Thank you so much for the love.”

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Carrie
Underwood and Brad Paisley were also show-stoppers with their opening jokes –
including about Blake Shelton and Miranda Lambert’s divorce.

“And
of course we can’t ignore the breakup that rocked our world,” Underwood
said, as the camera panned to Miss Piggy and Kermit the Frog.

“On
a completely unrelated topic, howdy Blake?” Paisley replied. The camera
panned to Shelton who laughed and clapped his hands, along with the audience.

“Did
you hear that duet that Blake did with Ashley Madison?” Paisley asked,
earning laughs from the audience at the Bridgestone Arena in Nashville,
Tennessee.

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“That
was with Ashley Monroe,” Underwood replied.

Shelton
confirmed Wednesday just hours before the awards show that he and his fellow
“Voice” mentor Gwen Stefani are dating. He and Lambert announced
their divorce in July.

Lambert,
who is also at the CMAs, is nominated for entertainer of the year, while
Shelton will perform later in the show.

Duets
kicked off the awards show: Eric Church and Hank Williams Jr performed
“Are You Ready for the Country” and John Mellencamp and Keith Urban
strummed their guitars during “Pink Houses.” Sam Hunt won over the
audience with his performance of “Take Your Time,” while Underwood
sang “Smoke Break.”

Little
Big Town, who also earned applause for their performance of “Girl
Crush,” won the first award of the live telecast for single of the year
for their No. 1 hit. The writers of “Girl Crush” won song of the
year.

“This
is about being brave and being bold,” Karen Fairchild said onstage with
her group. “Country radio, thanks for having the guts for playing
it.”

The
foursome, along with Church, walked into the arena as the most nominated act
with five. They lost music video of the year to Maddie & Tae’s “Girl
in a Country Song” and musical event of the year to Church and Urban. The
group, which includes Kimberly Schlapman, Jimi Westbrook and Phillip Sweet, is
also nominated for vocal group of the year, which it has won for the last three
years.

Little
Big Town is not up for the biggest honor: entertainer of the year. Church, who
announced he released a surprise album called “Mr. Misunderstood” on
Wednesday, is nominated for the top prize, pitting him against Garth Brooks,
Lambert, Chesney and last year’s winner, Luke Bryan.

WATCH: Carrie Underwood & Brad Paisley Take On Country’s Biggest Night

Kacey
Musgraves, Jason Aldean, Reba McEntire and Dierks Bentley will also perform
during the three-hour show, airing live on ABC. 

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