Brad Pitt & Angelina Jolie: The Early Years

Angelina Jolie and Brad Pitt attends the 'Inglourious Basterds' Premiere at the Grand Theatre Lumiere during the 62nd Annual Cannes Film Festival on May 20, 2009 in Cannes, France

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Getty Images

Angelina Jolie and Brad Pitt attends the 'Inglourious Basterds' Premiere at the Grand Theatre Lumiere during the 62nd Annual Cannes Film Festival on May 20, 2009 in Cannes, France

Angelina Jolie and Brad Pitt at the Ziegfeld Theater in New York City for the premiere of ‘The Good Shepherd’ on December 11, 2006

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WireImage

Angelina Jolie and Brad Pitt at the Ziegfeld Theater in New York City for the premiere of ‘The Good Shepherd’ on December 11, 2006

Brad Pitt and Angelina Jolie at ‘Mr. & Mr/s Smith’ premiere at the Mann Village in Los Angeles in June 2005

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WireImage

Brad Pitt and Angelina Jolie at ‘Mr. & Mrs. Smith’ premiere at the Mann Village in Los Angeles in June 2005

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AP

Brad Pitt and Angelina Jolie at ShoWest 2005 in Las Vegas

Angelina Jolie and Brad Pitt exiting Claridge’s Hotel in London on January 25, 2006

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FilmMagic

Angelina Jolie and Brad Pitt exiting Claridge’s Hotel in London on January 25, 2006

Brad Pitt and Angelina Jolie leave Hotel Belvedere in Davos, Switzerland on January 26, 2006

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AFP

Brad Pitt and Angelina Jolie leave Hotel Belvedere in Davos, Switzerland on January 26, 2006

Brad Pitt and Angelina Jolie in New York City on December 10, 2006

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WireImage

Brad Pitt and Angelina Jolie in New York City on December 10, 2006

Brad Pitt and Angelina Jolie leave the Temple Club restaurant in downtown Ho Chi Minh city in November 2006

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Getty Images

Brad Pitt and Angelina Jolie leave the Temple Club restaurant in downtown Ho Chi Minh city in November 2006

Angelina Jolie and Brad Pitt arrive at the premiere of ‘God Grew Tired of Us’ at the Pacific Design Center on January 8, 2007 in Los Angeles

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Getty Images

Angelina Jolie and Brad Pitt arrive at the premiere of ‘God Grew Tired of Us’ at the Pacific Design Center on January 8, 2007 in Los Angeles

brad pitt angelina jolie namibia ap 06 07 06

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AP

Brad Pitt and Angelina Jolie in Nammibia in June 2006

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NBC Photo: Chris Haston

Brad Pitt and Angelina Jolie in at the Golden Globes in 2007

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Associated Press

Angelina & Brad pose for press at the premiere of ‘A Mighty Heart’ in Cannes in May 2007

Brad Pitt & Angelina Jolie at The Venice Film Festival, September 2, 2007

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AP

Brad Pitt & Angelina Jolie at The Venice Film Festival, September 2, 2007

Brad Pitt & Angelina Jolie in NY, June 13, 2007

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AP

Brad Pitt & Angelina Jolie in NY, June 13, 2007

Brad Pitt & Angelina in Cannes, May, 2007

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AP

Brad Pitt & Angelina in Cannes, May, 2007

Brad Pitt & Angelina Jolie at Cannes, May 21, 2007

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AP

Brad Pitt & Angelina Jolie at Cannes, May 21, 2007

Brad Pitt & Angelina Jolie at the 'Oceans 13' premiere at Cannes, May 24, 2007

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AP

Brad Pitt & Angelina Jolie at the ‘Oceans 13’ premiere at Cannes, May 24, 2007

Brad Pitt & Angelina at the 'Oceans 13' premiere in LA, June 5, 2007

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AP

Brad Pitt & Angelina at the ‘Oceans 13’ premiere in LA, June 5, 2007

Angelina Jolie & Brad Pitt enjoy the show at the SAG Awards

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AP

Angelina Jolie & Brad Pitt enjoy the show at the SAG Awards

Brad Pitt and Angelina Jolie at the 2008 SAG Awards

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Access Hollywood

Brad Pitt and Angelina Jolie at the 2008 SAG Awards

Brad Pitt & Angelina Jolie arrive at the 2008 Independent Spirit Awards

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AP

Brad Pitt & Angelina Jolie arrive at the 2008 Independent Spirit Awards

Brad Pitt and Angelina Jolie at the premiere of ‘Kung Fu Panda’ at Cannes

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AP

Brad Pitt and Angelina Jolie at the premiere of ‘Kung Fu Panda’ at Cannes